75091-99-5

  • Product Name:4-(trifluoromethyl)cyclohexanone
  • Molecular Formula:C7H9F3O
  • Purity:99%
  • Molecular Weight:166.143
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Product Details;

CasNo: 75091-99-5

Molecular Formula: C7H9F3O

Chinese Factory Supply Top Purity 99% 4-(trifluoromethyl)cyclohexanone 75091-99-5 On Stock

  • Molecular Formula:C7H9F3O
  • Molecular Weight:166.143
  • Vapor Pressure:2.916mmHg at 25°C 
  • Refractive Index:1.395 
  • Boiling Point:156.246 °C at 760 mmHg 
  • Flash Point:53.308 °C 
  • PSA:17.07000 
  • Density:1.221 g/cm3 
  • LogP:2.30800 

4-(TRIFLUOROMETHYL)CYCLOHEXANONE(Cas 75091-99-5) Usage

Uses

4-(Trifluoromethyl)cyclohexanone (cas# 75091-99-5) is a compound useful in organic synthesis.

InChI:InChI=1/C7H9F3O/c8-7(9,10)5-1-3-6(11)4-2-5/h5H,1-4H2

75091-99-5 Relevant articles

Synthesis method of 4-substituent cyclohexanone liquid crystal intermediate

-

Paragraph 0056-0058, (2021/05/19)

The invention discloses a synthesis meth...

Csp3-H Trifluoromethylation of Unactivated Aliphatic Systems

He, Jiachen,Nguyen, Truong N.,Guo, Shuo,Cook, Silas P.

supporting information, p. 702 - 705 (2021/02/01)

A straightforward method for the undirec...

Direct C(sp3)?H Trifluoromethylation of Unactivated Alkanes Enabled by Multifunctional Trifluoromethyl Copper Complexes

Choi, Geunho,Lee, Geun Seok,Park, Beomsoon,Kim, Dongwook,Hong, Soon Hyeok

supporting information, p. 5467 - 5474 (2021/01/20)

A mild and operationally simple C(sp3)?H...

Aliphatic C-H Bond Oxidation with Hydrogen Peroxide Catalyzed by Manganese Complexes: Directing Selectivity through Torsional Effects

Milan, Michela,Bietti, Massimo,Costas, Miquel

supporting information, p. 2720 - 2723 (2018/05/22)

Substituted N-cyclohexyl amides undergo ...

75091-99-5 Process route

4-(trifluoromethyl)cyclohexan-1-ol
75091-92-8,75091-93-9,30129-18-1

4-(trifluoromethyl)cyclohexan-1-ol

4-(trifluoromethyl)cyclohexan-1-one
75091-99-5

4-(trifluoromethyl)cyclohexan-1-one

Conditions
Conditions Yield
With Dess-Martin periodane; In dichloromethane; at 20 ℃; for 2h;
94.6%
4-(trifluoromethyl)cyclohexan-1-ol; With C10H20NO2(1-); sodium hydrogencarbonate; In chloroform; water; at 20 ℃; for 0.25h;
With trichloroisocyanuric acid; In chloroform; water; for 6h;
88.5%
With pyridinium chlorochromate; In dichloromethane; at 20 ℃; for 2h;
57%
With CrO3/silica gel; In various solvent(s); at 40 ℃; for 4h; under 165013 Torr;
46 % Chromat.
C<sub>12</sub>H<sub>20</sub>F<sub>3</sub>NO

C12H20F3NO

N-(4-(trifluoromethyl)cyclohexyl)pivalamide

N-(4-(trifluoromethyl)cyclohexyl)pivalamide

4-(trifluoromethyl)cyclohexan-1-one
75091-99-5

4-(trifluoromethyl)cyclohexan-1-one

Conditions
Conditions Yield
With C40H68F6MnN4O6S2Si2; dihydrogen peroxide; acetic acid; In acetonitrile; at -40 ℃; for 0.5h; diastereoselective reaction;
96%

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